You removed the quote source information, so now Nightwalkerxx won't have gotten a notification that you asked a question that s/he could answer. (You will get one for this post, because I preserved that information.)
Try the following:
a) Format the microSD card as exFAT with the Panasonic SD Formatter and its Size Adjustment option set to On.
b) Following 'a', enter a command prompt (on Vista+, type 'cmd' in the Start Menu; otherwise, Applications/Accessories/Command Prompt) and type:
Code:
format <Drive:> /a:64k /fs:fat32
Step 'a' should make the partition start at the right place, and step 'b' would make it FAT32 instead of exFAT, but with huge
allocation units (/
a:64k).
I have not personally tested this, or even the
support for 64 GiB microSD cards in CATSFC and TempGBA, as I do not have a 64 GiB microSD card.