Are you sure you run it in PSTV?Loading a game works (however there was no sound). If I then choose 'close content' and load another ROM, it crashes every time.
I'm using the zip files from a no-intro ROMset and the 'load archive' option.
https://mega.nz/#F!xtdUALJb!a0SpUy18W7ndIBWbrg0T_w