I have now tried every revision of devkitARM on that site and revisions older than r47 all don't compile or freeze after the boot animation.
Maybe the revisions of libnds and libfat don't quite work as I use the latest ones and trying the ones from ahezard and compiling them with r42 didn't work, I really am not capable to get this working.
I wouldn't have been able to contribute with my skill set anyway but trying out some of that bleeding edge stuff before binaries get released would have been fun.
@dawiid I had a similar problem, I formatted my SD card with 32 KB cluster and then unlaunch worked again, maybe this helps you as well.
Selecting default sector size on my 32 GB card set the sector size to 64 KB which caused problems.