Before we proceed with that you sure your hekate_ipl.ini is named correctly, and you used the correct bootloader to boot with correct CFW file?
Ok so I renamed the file and put it under the other boot loader and then the subfolder Ini and boot options only showed up in more configs but they all showed up with this error message (Error while loading fss0:atmosphere/packadge3 Wrong ini cfg or missing files/
Failed to launch HOS/