Anything what wasn't blocked by 8.1/9.0 version of TWL_FIRM can be used again if you install the 1.0 version of DS Cart White List. For n3DS users this is the best you can do and isn't any worse then using a "broken" DS Cart White list. The "backup" white list it might have might actually be newer on n3DS then the 1.0 version we would be installing, so you might get worse compatibility with a broken white list on the n3DS.
Which backup white list? I don't think that there is another white list than the one we change.
As for old 3DS, theoretically a 1.0 TWL_FIRM with a broken DS Cart White list would have the best flashcart compatibility possible. But 2.0 is the oldest version of TWL available and I don't know if a broken DS Cart White list would be any better then having a 1.0 DS Cart White list. Until someon can dump v1.0 TWL_FIRM we will never know.
I don't think that any flashcards were blocked with TWL_FIRM between 1.0 and 2.0. I don't even think that there are any flashcards that work with 1.0 but not with 2.0. Whitelist blocks are probably the only ones from 1.0 to 2.0.
Someoone mentioned somewhere that it could be possible to dump the DS Cart White list from a 1.0 DSi. But I doubt that would be usable on the 3DS. First of all CIAs did not exist in their current form when the DSi was around and thus the way the files were signed is probably not compatible or modifications would have to be made to it for it to install onto a 3DS which would break the file signatures and render the process pointless.
The DSi never had a version "1.0". Using that would probably be equal to using a broken whitelist on the 3DS.