Actually, it seems I was using the right Apps, but not understanding it correctly.
USB Image Tool: Once Opened, do NOT change any Settings. If in Volume Mode, go to Device Mode. Select Drive to Copy, and Select Backup. Enter a Name then wait. Once finished, put the new Card in and Select Restore and select the Image.
EaseUS: Once the Restore Process is complete you will notice the Size is less than the new Card. Open EaseUS and find the Drive Letter for the Card. Right Click on it, and Select Resize/Move Partition. Make sure to Select the Middle Section's Right Side Adjustment, and move to the Right to encompass the rest of the Card. Select OK, then hit Apply.
Should be good to go now. But to make sure, Run the Error Checking option through Windows (Right Click, Properties, Tools Tab, Error Checking, your choice to also select the bottom one).
Not sure, but I think it would not be a good idea to use a USB Card Reader. Preferably, a Built-In Card Reader would be the way to go. I tried to copy over a few PSX Games, and I had problems with the USB Reader, but the Built-in worked perfectly.