Speaking of windows, is there anyway I can gain access to my windows part of my HDD? I would like to get things out of there to here without having to keep switching and moving files via usb.
Yes, you should be able to edit /etc/fstab as root (Use sudo gedit /etc/fstab and add in the drive pertaining to your windows install, this will allow it to mount on boot). Scripts really aren't nessesary for this, and I cannot understand why people don't just use FStab as it does the same thing.
Linux uses /dev/sdx syntax for it's drives. You need to find out which one your windows install is represented by and substitute it in the tutorial below for /dev/sdx
In fact, here's a tutorial. Psychocats is an awesome website btw, great for New Ubuntu/Debian/Mint users http://www.psychocats.net/ubuntu/mountwindowsfstab#fstab
I might actually go with Debian Mint over my Debian Sid Install. Sid breaks alot, but that's what entertains me.
Also, there's #! aka Crunchbang, based on Debian Testing (Wheezy), it's primary environments are OpenBox and Xfce, it's extremely lightweight, but you may be able to install KDE and other environments as well.
Either way, take it easy and do it slowly when you're testing out Linux. The more time you spend with it and not rush through it, the easier it will be.