To be honest, I was expecting a blank hekate_ipl.ini file. So by the looks of it, your hekate_ipl.ini file is highly outdated because its referring to a pack that no longer exists (SDFiles was eventually renamed to Kosmos but that was discontinued a while ago). You now have 2 options: you can either edit the file yourself or find another pre-configured file. I'm guessing you would prefer the latter so I will give you 2 more options to pick from. You can get one from DeepSea which is a spiritual successor to Kosmos (or SDFiles in your case) or, and this is the one I recommend, download a hekate_ipl.ini file from SDSetup. The reason I prefer SDSetup is that it lets me choose what files and tools I want to download then use unlike DeepSea which floods me with a lot of unnecessary bloat. Either way, both of them will give you a setup of Hekate that can boot into Atmosphere.
My fault, mate. You´re right. I checked the Hekate release .zip file, it does not include the .ini file. It´s an old file that exists on my sd card. Sorry. I will get a pre-configured one. Thanks so far.