What Foxi4 said.
Most previous work on anything to do with the DS wifi, once homebrew was made anyway, has been more to do with custom tracks/levels, cheats and the like. As most of that was local (hence Mario Kart track swapping and pokemon cheating) and the wifi stuff was mainly a glorified lobby and multicast server (I think) it meant there was no real need to do anything from the hacker side of things. Sadly the leaked SDK and any subsequent leaks (the DS 3d, also any source code left in games*) did not have anything of note, not the SDK probably would. Naturally some people did try to sniff connections, I am sure you probably read the same post as myself somewhere that mentioned the encrypted packets and though I think at least some of it was plaintext after handshakes nobody even really went for injection; if you can cheat and modify the games then why bother.
*puzzle quest lacks it but I am not sure if any of the other lua using games (El Tigre make my mule and one other that I can not recall right now may be different, it was a Japanese music/rhythm/puzzle game I think). Edit, it was Theta.
On firmware. Not sure entirely. The firmware was updated to support wifi (indeed triggering the need for an update to the custom firmware which had previously used the space) but I am not sure how deeply it draws -- for most games and homebrew it would be the location of the saved settings but homebrew like DSOrganize (
http://www.dragonminded.com/ndsdev/dsorganize/ ) instead had the option to pull settings from saved data via DLDI and the like. Whether this speaks to the firmware being unnecessary or not remains to be seen, generally people were told to run a wifi using game but that might have just been so it could have settings to draw from.
You may find something of interest in
http://fwnitro.caitsith2.net/ as it could fiddle with something wifi related (though looking at it now it seems more of a firmware activated cheat or something), not sure if creebome or Loopy's minimalist firmware even support wifi let alone have something of note in them.
Interesting work though, I shall await your results.