Managed to get my US XL over to a PAL emunand last night, not after some hiccups though.
After installing the necessary CIA files and injecting the emunand dump with the SecureInfo tool and running a System Format on it, my sysnand became incredibly unstable, to the point where it wouldn't boot if there was a cartridge inserted. It also reverted the DS profile exploit, so thankfully the browser still worked as a way to get to the rxtools menu. After entering emunand again I was greeted with the European setup menu, and once that was finished thankfully it seemed to fix everything that was wrong with the sysnand.
This was pretty much just done out of curiosity, and everything seems to be stable now. Likely going to revert to prior NAND dumps though since I have no current use for a PAL nand. Once a N3DS method makes its way out, I'll likely be doing this again to get my PAL system over to US.
If there's enough interest I'll try to write up a more user-friendly tutorial later on.