Did you downgrade the 3DS to 4.5 at any point in time using Gateway?Well, I have followed all applicable instructions in the wiki and from what people suggested here. I posted a list a few posts above.
No matter what I did, always Luma3DS gives a black screen and freezes the system, and always Reinand or Cakes will play the DS flashcard.
From what I see it freezes exactly at the point were the 3DS loads the DS firmware (the point were the screens go off and then starts at DS mode).