Well, yes, but just because it'd get her where she wants doesn't mean she'd bother doing what is basically an emergency play just to gain power.
And even if it does happen, I'd be perfectly fine with it. (Heck, she'd probably get more done!)
It's my understanding that the VP has to be involved in that process for it to even begin though, no?
Bad news: Pence is, as was discussed, a spineless coward.
Good news: Pence basically ditched him earlier today after Trump called him a traitor for
literally just stating that he cannot do things that his position does not grant him the power to do, so he's already made that decision. Now he just has to speak up.